A crossed-beam technique incorporating time-of-flight analysis and coi
ncidence counting of the collision products, recently used in this lab
oratory to study one-electron capture in collisions of H+ ions with gr
ound-state oxygen atoms, has been adapted to allow measurements of the
corresponding cross sections for ionization for the first time. Cross
sections for the single ionization of O atoms have been determined wi
thin the range 34-100 keV. These cross sections pass through a peak va
lue at an energy of about 60 keV. At higher energies, the process of i
onization rather than electron capture becomes the main source of O+ p
roduction. O+ formation for n > 2 was too small to detect in the energ
y range considered. It is also shown that although production of O2+ t
hrough transfer ionization is quite significant. the yield of O2+ from
pure ionization is unimportant.