Photoreflectance (PR) and photoluminescence (PL) measurements have bee
n carried out at 77 K on single crystals of CuAlxGa1-xSe2 alloys grown
by the chemical vapor transport method. Energies of excitons associat
ed with uppermost valence bands have been determined as a function of
composition based on the analysis of PR spectra. Spin-orbit and crysta
l field splittings have been obtained. PL spectra exhibited an exciton
-related line, a peak due to free-to-acceptor transition and a deep le
vel emission band. These PL lines and peaks are discussed in terms of
the compositional dependence of the exciton energy.