POLARIZED-PI FRONTIER MOLECULAR-ORBITAL (PPFMO) AND EXPERIMENTAL STUDIES OF FACIAL SELECTIVITY IN ELECTROPHILIC ATTACKS ON SUBSTITUTED ALKENES

Authors
FRANCK RW KAILA N BLUMENSTEIN M GEER A HUANG XL DANNENBERG JJ
Citation
Rw. Franck et al., POLARIZED-PI FRONTIER MOLECULAR-ORBITAL (PPFMO) AND EXPERIMENTAL STUDIES OF FACIAL SELECTIVITY IN ELECTROPHILIC ATTACKS ON SUBSTITUTED ALKENES, Journal of organic chemistry, 58(20), 1993, pp. 5335-5337
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
58
Issue
20
Year of publication
1993
Pages
5335 - 5337
Database
ISI
SICI code
0022-3263(1993)58:20<5335:PFM(AE>2.0.ZU;2-1
Abstract
Polarized pi-frontier orbital theory (PPFMO) is applied to the protona tion and sulfenylation of several dihydrofurans and dihydropyrans of i mportance in sugar chemistry. The PPFMO method correctly predicts the observed selectivities for all experimentally observed cases, two of w hich are reported here for the first time.