DIFFERENTIAL MOLECULAR-WEIGHT DISTRIBUTIONS IN HIGH-PERFORMANCE SIZE-EXCLUSION CHROMATOGRAPHY

Authors
Citation
Dw. Shortt, DIFFERENTIAL MOLECULAR-WEIGHT DISTRIBUTIONS IN HIGH-PERFORMANCE SIZE-EXCLUSION CHROMATOGRAPHY, Journal of liquid chromatography, 16(16), 1993, pp. 3371-3391
Citations number
9
Categorie Soggetti
Chemistry Analytical
ISSN journal
01483919
Volume
16
Issue
16
Year of publication
1993
Pages
3371 - 3391
Database
ISI
SICI code
0148-3919(1993)16:16<3371:DMDIHS>2.0.ZU;2-H
Abstract
The definition and derivation of differential molecular weight distrib ution functions are thoroughly discussed. Common errors appearing in t he literature are revealed and corrected. For high performance size ex clusion chromatography (HPSEC), the importance of the calibration curv e and its slope is discussed, and the application to gel permeation ch romatography (GPC) is illustrated with simulations and real data.