An important development in polycrystalline Cu(In,Ga)Se2 (CIGS) thin-f
ilm photovoltaic solar cells is the attainment of a high voltage devic
e simultaneous with state-of-the-art conversion efficiency. This lette
r describes a CIGS-based solar cell that demonstrates an open-circuit
voltage ( V(oc)) approaching 700 mV and a total-area conversion effici
ency of 12.2%. The high value of V(oc) was achieved by grading In/Ga t
hrough the absorber by a computer-controlled physical vapor deposition
(PVD) process that utilizes variable metal fluxes.