Gy. Meng et al., MODEL FOR THE VAPORIZATION OF MIXED ORGANOMETALLIC COMPOUNDS IN THE METALORGANIC CHEMICAL-VAPOR-DEPOSITION OF HIGH-TEMPERATURE SUPERCONDUCTING FILMS, Applied physics letters, 63(14), 1993, pp. 1981-1983
A model of the vaporization and mass transport of mixed organometallic
s from a single source for thin film metalorganic chemical vapor depos
ition is presented. A stoichiometric gas phase can be obtained from a
mixture of the organometallics in the desired mole ratios, in spite of
differences in the volatilities of the individual compounds. Proper f
ilm composition and growth rates are obtained by controlling the veloc
ity of a carriage containing the organometallics through the heating z
one of a vaporizer.