PIEZOELECTRIC DETECTION OF WATER WITH A SEPARATED ELECTRODE

Citation
Wh. Zhu et al., PIEZOELECTRIC DETECTION OF WATER WITH A SEPARATED ELECTRODE, Analytical chemistry, 65(19), 1993, pp. 2568-2571
Citations number
27
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00032700
Volume
65
Issue
19
Year of publication
1993
Pages
2568 - 2571
Database
ISI
SICI code
0003-2700(1993)65:19<2568:PDOWWA>2.0.ZU;2-V
Abstract
A new detector of water based on the piezoelectric crystal with separa ted electrode (PCSE) is proposed. The frequency response of the PCSE t o the dielectric constant of nonelectrolyte solution is derived. The d etector was applied to determine the microcontent of water in organic solvents. The detection limits are 0.022, 0.013, and 0.010 g/L in acet one, tetrahydrofuran, and dioxane, respectively. For the water content in ethanol, linear and nonlinear regression methods are employed, and the average relative errors of prediction are 1.67% and 2.77%, respec tively.