Using the sessile drop method under vacuum, the wettability of monocry
stalline alpha-SiC by Au-Si alloys is studied at 1373 K. Additions of
Si to Au lead to a strong decrease of the contact angle from theta >>
90-degrees to theta << 90-degrees. This effect is obtained without sig
nificant reactivity and is due to adsorption of Si at the Au/SiC inter
face, with the formation of a strong chemical bond localised at the in
terface. Experimental evidence is given showing that oxygen, present i
n the furnace as an impurity, reinforces the beneficial effect of Si o
n wetting and can lead to nearly perfect wetting.