Mg. Norton et al., XENON EMISSION ACCOMPANYING FRACTURE OF XENON-IMPLANTED CUBIC ZIRCONIA, Journal of the American Ceramic Society, 76(8), 1993, pp. 2076-2080
The emission of xenon following the fracture of xenon-implanted cubic
zirconia has been studied using mass spectrometry. All samples showed
intense Xe bursts at failure. Order of magnitude estimates of the amou
nt of Xe released suggest that micrometer-scale regions of the tensile
surface on either side of the fracture surface of these samples do no
t show sufficient damage to account for this emission. However, SEM mi
crographs of the fracture surface show evidence for extensive microcra
cking immediately adjacent to the tensile surface. It is believed that
these microcracks are formed when the advancing crack encounters the
tensile stresses immediately below the Xe-implanted surface layer and
disrupts the Xe inclusions produced by implantation. Some samples also
show Xe bursts prior to failure; SEM observations of these samples sh
ow shallow conchoidal cracks on the tensile surface, which apparently
form during loading and would account for the release of Xe prior to f
ailure.