Jkr. Weber et al., ENHANCED FORMATION OF CALCIA-GALLIA GLASS BY CONTAINERLESS PROCESSING, Journal of the American Ceramic Society, 76(8), 1993, pp. 2139-2141
Glass formation from melts of 44CaO.56Ga2O3 (mol %) was investigated u
nder containerless conditions obtained by acoustically stabilized aero
dynamic levitation in combination with laser beam heating. The critica
l cooling rate for glass formation was R(c) < 100-degrees-C/s, much le
ss than values reported in the literature (R(c) = 550-degrees +/- 120-
degrees-C/s and ca. 350-degrees-C/s) for pendant drops of this composi
tion attached to Pt-Rh thermocouples. High values of R(c) in pendant d
rop experiments were confirmed for the specimens used in this work.