THE HIGH-RESOLUTION FTIR SPECTRUM OF JET-COOLED CH3CF2CL

Authors
MCNAUGHTON D EVANS C
Citation
D. Mcnaughton et C. Evans, THE HIGH-RESOLUTION FTIR SPECTRUM OF JET-COOLED CH3CF2CL, Journal of molecular spectroscopy, 182(2), 1997, pp. 342-349
Citations number
15
Categorie Soggetti
Spectroscopy,"Physics, Atomic, Molecular & Chemical
Journal title
Journal of molecular spectroscopy → ACNP
ISSN journal
00222852
Volume
182
Issue
2
Year of publication
1997
Pages
342 - 349
Database
ISI
SICI code
0022-2852(1997)182:2<342:THFSOJ>2.0.ZU;2-3
Abstract
The infrared spectrum of HCFC-142b, CH3CF2Cl, has been recorded at hig h and low resolution using a supersonic jet-FTIR spectrometer system. Molecular parameters for a number of vibrational states have been obta ined from rovibrational analyses of the C-type bands nu(14) (1192 cm(- 1)) and nu(15) (967 cm(-1)), the A-type band nu(7) (905 cm(-1)), and t he B-type bands nu(5) (1234 cm(-1)) and nu(7) + nu(11) (1215 cm(-1)). A rotational temperature of ca. 50 K in the jet expansion has been est imated from a comparison of the experimental spectrum with band simula tions calculated using the resultant molecular constants. (C) 1997 Aca demic Press.