TRIFLUOROMETHYLFLUOROCARBENE FORMATION AND REACTIONS UNDER C2F5SIF3 PULSED ADIABATIC-COMPRESSION PYROLYSIS

Authors
BURAVTSEV NN GERMAN LS GRIGOREV AS KOLBANOVSKII YA OVSYANNIKOV AA VOLKONSKII AY
Citation
Nn. Buravtsev et al., TRIFLUOROMETHYLFLUOROCARBENE FORMATION AND REACTIONS UNDER C2F5SIF3 PULSED ADIABATIC-COMPRESSION PYROLYSIS, Mendeleev communications, (4), 1993, pp. 133-134
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
4
Year of publication
1993
Pages
133 - 134
Database
ISI
SICI code
0959-9436(1993):4<133:TFARUC>2.0.ZU;2-#
Abstract
The formation of :CFCF3, SiF4 and (cis+trans)-2-C4F8 is demonstrated u nder the strictly homogeneous pyrolysis of C2F5SiF3, using kinetic spe ctroscopy (at 250 and 465 nm) and chromatographic analysis, respective ly. Pyrolysis of 2-C4F8 under the same conditions leads to the formati on of an intermediate (C4) which reveals absorption at 250 nm.