Mannose, galactose and glucose thiosemicarbazones, and mannose thiocar
bohydrazones exist in DMSO solutions as tautomeric mixtures of pyranos
e and linear hydrazone forms, but in solutions of galactose and glucos
e thiocarbohydrazones there are also hexahydro-1,2,4,5-tetrazine-3-thi
one tautomers.