RUTHENIUM-CATALYZED HYDROGENATION OF DIMETHYL OXALATE TO ETHYLENE-GLYCOL

Citation
Ht. Teunissen et Cj. Elsevier, RUTHENIUM-CATALYZED HYDROGENATION OF DIMETHYL OXALATE TO ETHYLENE-GLYCOL, Chemical communications, (7), 1997, pp. 667-668
Citations number
5
Categorie Soggetti
Chemistry
Journal title
ISSN journal
13597345
Issue
7
Year of publication
1997
Pages
667 - 668
Database
ISI
SICI code
1359-7345(1997):7<667:RHODOT>2.0.ZU;2-4
Abstract
Dimethyl oxalate is efficiently hydrogenated to ethylene glycol under mild conditions [p(H-2) 70 bar; 100 degrees C] using a ruthenium catal yst based on Ru(acac)(3) and MeC(CH(2)PPh(2))(3).