V. Butun et al., SYNTHESIS AND AQUEOUS-SOLUTION PROPERTIES OF NOVEL HYDROPHILIC-HYDROPHILIC BLOCK-COPOLYMERS BASED ON TERTIARY AMINE METHACRYLATES, Chemical communications, (7), 1997, pp. 671-672
A series of near-monodisperse novel diblock copolymers based on tertia
ry amine methacrylates has been synthesised using group transfer polym
erisation chemistry; subtle differences in basicity between the two bl
ocks lead to interesting aqueous solution behaviour, including pH-indu
ced micellisation and very high surface activity.