RADICAL-CATION DIELS-ALDER REACTION OF INDOLES AND EXOCYCLIC DIENES

Citation
O. Wiest et E. Steckhan, RADICAL-CATION DIELS-ALDER REACTION OF INDOLES AND EXOCYCLIC DIENES, Tetrahedron letters, 34(40), 1993, pp. 6391-6394
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
34
Issue
40
Year of publication
1993
Pages
6391 - 6394
Database
ISI
SICI code
0040-4039(1993)34:40<6391:RDROIA>2.0.ZU;2-0
Abstract
A convergent of [b]-annealed tetrahydrocarbazoles through a radical ca tion Diels-Akler reaction is described. The reaction is induced by pho to electron transfer (PET). The previously predicted stepwise mechanis m of this reaction type is proved by stereochemical analysis of the pr oducts.