REFORMATSKY REACTION ON THIOCARBONYL COMPOUNDS - NEW C-C BOND-FORMINGREACTION

Citation
M. Chandrasekharam et al., REFORMATSKY REACTION ON THIOCARBONYL COMPOUNDS - NEW C-C BOND-FORMINGREACTION, Tetrahedron letters, 34(40), 1993, pp. 6439-6442
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
34
Issue
40
Year of publication
1993
Pages
6439 - 6442
Database
ISI
SICI code
0040-4039(1993)34:40<6439:RROTC->2.0.ZU;2-V
Abstract
Reformatsky reagents are shown to undergo facile C-C bond formation on trithiocarbonates, xanthates, thione and dithioesters through carboph ilic addition yielding products formed by elimination of either sulphu r or alkylthio group.