The sensitivity of magneto-optical spectra to alloy chemical ordering
is established. This is demonstrated for a new ordered Co3Pt phase, wh
ich was synthesized in thin film form using molecular beam epitaxial g
rowth. This compound consists of alternating planes of Co and CoPt ato
ms with a hexagonal ABAB... layer sequence. The chemical ordering is a
ccompanied by a substantial electronic structure change as reflected i
n a new peak in magneto-optical spectra at approximately 3.2 eV photon
energy.