DIPHENYL METHYLPHOSPHONATE AS A PHOSPHONYLATION REAGENT WITH HIGH DIASTEREOSELECTIVITY AT PHOSPHORUS

Authors
MORIARTY RM TAO AP CONDEIU C GILARDI R
Citation
Rm. Moriarty et al., DIPHENYL METHYLPHOSPHONATE AS A PHOSPHONYLATION REAGENT WITH HIGH DIASTEREOSELECTIVITY AT PHOSPHORUS, Tetrahedron letters, 38(15), 1997, pp. 2597-2600
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
15
Year of publication
1997
Pages
2597 - 2600
Database
ISI
SICI code
0040-4039(1997)38:15<2597:DMAAPR>2.0.ZU;2-1
Abstract
Reaction of diphenyl methylphosphonate with lithium alkoxides generate d in situ from alcohols and butyllithium gives phenyl alkyl methylphos phonate diesters even with hindered alcohols and with high diastereose lectivity at phosphorus. (C) 1997 Elsevier Science Ltd.