1,6-EPITHIO-BETA-D-GLUCOPYRANOSE AND 1,6-EPISELENO-BETA-D-GLUCOPYRANOSE - USEFUL ADJUNCTS IN THE SYNTHESIS OF 6-DEOXY-BETA-D-GLUCOPYRANOSIDES

Authors
STICK RV TILBROOK DMG WILLIAMS SJ
Citation
Rv. Stick et al., 1,6-EPITHIO-BETA-D-GLUCOPYRANOSE AND 1,6-EPISELENO-BETA-D-GLUCOPYRANOSE - USEFUL ADJUNCTS IN THE SYNTHESIS OF 6-DEOXY-BETA-D-GLUCOPYRANOSIDES, Tetrahedron letters, 38(15), 1997, pp. 2741-2744
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
15
Year of publication
1997
Pages
2741 - 2744
Database
ISI
SICI code
0040-4039(1997)38:15<2741:1A1>2.0.ZU;2-1
Abstract
The treatment of derivatives of 1,6-epithio- and 1,6-episeleno-beta-D- glucopyranose with various carbohydrate alcohols in the presence of N- iodosuccinimide/triflic acid gives rise to di sulfides and diselenides , respectively, which may be transformed to the desired 6-deoxy-beta-D -glucopyranosides. (C) 1997 Elsevier Science Ltd.