The poisoning of a commercial resin, Amberlite XAD-4, has been induced, und
er the regular conditions used for phenols elimination of effluents in the
coal chemistry industry. It has been observed that after successive regener
ation cycles with sodium hydroxide, a progressive impairment of the adsorbe
nt is produced, caused by the irreversible adsorption (poisoning) of high m
olecular compounds present in the effluent, like the naphthalene. Laborator
y assays state the first hypothesis about the poisoning mechanisms. On the
other hand, several organic solvents have been tested for the chemical rege
neration of the resin, acetone and ethanol, obtaining satisfactory results.