Polymer gel template for porous TiO2 production

Citation
Ra. Caruso et al., Polymer gel template for porous TiO2 production, BER BUN GES, 102(11), 1998, pp. 1540-1543
Citations number
20
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN journal
0940483X → ACNP
Volume
102
Issue
11
Year of publication
1998
Pages
1540 - 1543
Database
ISI
SICI code
0005-9021(199811)102:11<1540:PGTFPT>2.0.ZU;2-5
Abstract
Porous networks of titanium dioxide have been produced using polymer gels a s templates. Titanium dioxide is well known for its semiconductor and catal ysis properties, and for being a very stable material. The porous polymer g els are produced in aqueous surfactant solutions. Following cleaning and so lvent exchange procedures the titanium precursor can be incorporated within the gel and hydrolysed. The organic material is removed during calcination leaving the structured titanium dioxide. Both the rutile and anatase forms of titanium dioxide can be produced. The resulting crystal structure and t he surface area of the oxide are important for determining its scope of app lication. These properties have been studied using electron microscopy, X-r ay diffraction and gas sorption.