B. Mayer et al., Estimation of surface actinic flux from satellite (TOMS) ozone and cloud reflectivity measurements, GEOPHYS R L, 25(23), 1998, pp. 4321-4324
Recently, a method has been proposed to estimate ultraviolet (UV) spectral
irradiances at the Earth's surface, from satellite-based measurements of oz
one and cloud reflectivity. Here, we extend this method to the determinatio
n of spectral actinic fluxes needed for the calculation of photodissociatio
n rate coefficients. It is shown that the modification of actinic flux by c
louds is closely approximated by the cloud reduction factor applicable to t
he irradiance, if considering averages over area or time instead of instant
aneous point data. The conversion of irradiance estimates into actinic flux
estimates introduces additional errors, but for most practical situations
these fall below 10 to 20% in the UV spectral region, where the relevant ph
otolytic reactions have their maximum sensitivity. Based on these results,
large satellite-derived data sets (e.g., ozone column and cloud reflectivit
y from the Total Ozone Mapping Spectrometer, TOMS) can be utilized to estim
ate near-surface photolysis rate coefficients on a global scale.