Hypervalent phosphorus compounds as ligands

Authors
Morrow, JR Savino, P Huang, LY Perri, A
Citation
Jr. Morrow et al., Hypervalent phosphorus compounds as ligands, HETEROAT CH, 9(7), 1998, pp. 699-702
Citations number
17
Categorie Soggetti
Chemistry
Journal title
HETEROATOM CHEMISTRY
ISSN journal
10427163 → ACNP
Volume
9
Issue
7
Year of publication
1998
Pages
699 - 702
Database
ISI
SICI code
1042-7163(1998)9:7<699:HPCAL>2.0.ZU;2-R
Abstract
Four new metal ion complexes with phosphatrane ligands have been isolated a nd characterized including AuBr3(SP(OCH2CH2)(3)N), AuI3(SP(OCH2CH2)(3)N), A uBr3(OP(OCH2CH2)(3)N) and [MeHg(SP(OCH2CH2)(3)N)](NO3). The phosphatranes a re examples of hypervalent phosphorus ligands which ave bound through oxyge n or sulfur to the metal ion. These complexes are unique models for propose d intermediates in metal ion promoted phosphate ester substitution reaction s. (C) 1998 John Wiley & Sons, Inc.