Mossbauer study on characterization of Co[Fe(CN)(5)NH3]center dot xH(2)O

Authors
Einaga, Y Gu, ZZ Kobayashi, Y Sato, O Iyoda, T Ambe, F Hashimoto, K Fujishima, A
Citation
Y. Einaga et al., Mossbauer study on characterization of Co[Fe(CN)(5)NH3]center dot xH(2)O, HYPER INTER, 116(1-4), 1998, pp. 159-166
Citations number
19
Categorie Soggetti
Physics
Journal title
HYPERFINE INTERACTIONS
ISSN journal
03043843 → ACNP
Volume
116
Issue
1-4
Year of publication
1998
Pages
159 - 166
Database
ISI
SICI code
0304-3843(1998)116:1-4<159:MSOCOC>2.0.ZU;2-6
Abstract
The electronic states of Fe atoms in Co[Fe(CN)(5)NH3] . xH(2)O were studied by means of Fe-57 Mossbauer spectroscopy. The Mossbauer spectra of Co[Fe(C N)(5)NH3] . 6H(2)O show the coexistence of mixed valences for the Fe atoms and a magnetic relaxation at 4 K. When water molecules were removed, electr on transfer from Co to Fe occurred.