Preparation and characterization of a novel class of chloride alkoxides ofberyllium(II), magnesium(II), zinc(II), and tin(II) with niobium(V)

Authors
Bhagat, M Singh, A Mehrotra, RC
Citation
M. Bhagat et al., Preparation and characterization of a novel class of chloride alkoxides ofberyllium(II), magnesium(II), zinc(II), and tin(II) with niobium(V), I J CHEM A, 37(9), 1998, pp. 820-825
Citations number
19
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
37
Issue
9
Year of publication
1998
Pages
820 - 825
Database
ISI
SICI code
0376-4710(199809)37:9<820:PACOAN>2.0.ZU;2-Y
Abstract
Heterobimetallic chloride isopropoxide derivatives of the types, [{M[Nb(OPr i)(5)Cl](mu-Cl)}(2)] and [M{Nb(OPri)(5)Cl}(2)] [where M = Be(II), Mg(II), Z n(II) and Sn(II)] have been synthesized by the reactions of metal chlorides with niobium pentaisopropoxide in 1:1 and 1:2 molar ratios, respectively. All these novel derivatives have been characterized by elemental analyses, molecular weight measurements, and spectroscopic (IR, H-1, C-13 and Sn-119 NMR) studies.