Studies on cis and trans influence in alkylcobaloximes with different axial bases

Authors
Gupta, BD Qanungo, K Singh, V",Shobini
Citation
Bd. Gupta et al., Studies on cis and trans influence in alkylcobaloximes with different axial bases, I J CHEM A, 37(8), 1998, pp. 707-711
Citations number
31
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
37
Issue
8
Year of publication
1998
Pages
707 - 711
Database
ISI
SICI code
0376-4710(199808)37:8<707:SOCATI>2.0.ZU;2-V
Abstract
Thirteen alkyl cobaloximes RCo(L,)B with two equatorial ligands L (L=dmgH a nd dpgH) and with three different bases B (gamma -picoline, imid and benzim id) have been synthesised (78 complexes in all). The cis influence has been studied using UV-Vis, IR and LH NMR techniques. The results show that the cis influence follows the order : dpgh > dmgH and the result match with tho se of our previous studies.