Electrical resistivity of graphite intercalation compounds with SbCl5 and ICl near phase transitions

Authors
Vovchenko, LL Matsui, LY Litvinenko, SV Kotsyuba, AN
Citation
Ll. Vovchenko et al., Electrical resistivity of graphite intercalation compounds with SbCl5 and ICl near phase transitions, INORG MATER, 34(12), 1998, pp. 1222-1226
Citations number
14
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
INORGANIC MATERIALS
ISSN journal
00201685 → ACNP
Volume
34
Issue
12
Year of publication
1998
Pages
1222 - 1226
Database
ISI
SICI code
0020-1685(199812)34:12<1222:EROGIC>2.0.ZU;2-Y
Abstract
Phase transitions in the intercalant layer of graphite intercalation compou nds with SbCl5 and ICI were studied in the temperature range 77-300 K. In S bCl5-intercalated disordered pyrolytic graphite, the SbCl6 phase was found to turn from, a quasi-crystalline to quasi-liquid state at 265-275 K. An an alogous transition in the ICI layer was observed at 290-320 K for both high ly oriented and disordered graphites.