A. Nara et H. Itoh, LOW DIELECTRIC-CONSTANT INSULATOR FORMED BY DOWNSTREAM PLASMA CVD AT ROOM-TEMPERATURE USING TMS O-2/, JPN J A P 1, 36(3B), 1997, pp. 1477-1480
The present an insulator with a dielectric constant lower than 3.0, th
ermal stability up to 500 degrees C and good gap-filling characteristi
cs. This insulator was formed by downstream plasma chemical vapor depo
sition (CVD) at room temperature using tetra-methylsilane (TMS)/O-2 ga
ses. It contained a large amount of water in the as-deposited state. A
nnealing at 350 degrees C resulted in a decrease in the water content
of the insulator, and the insulator did not absorb water after the ann
ealing. The film is constructed from Si-O and Si-CH3 bonds, which prod
uce a low dielectric constant and high thermal stability.