Cluster tool furnace technology was used to control the growth of extr
emely uniform ultra-thin 1.5 nm to 3 nm SiO2 layers on Si. The transit
ion from Fowler-Nordheim tunneling to direct tunneling electron inject
ion for sub-3-nm oxide poly-Si gate metal-oxide-silicon capacitor stru
ctures is described and the influence on the oxide reliability is disc
ussed. It is shown that oxide breakdown can still occur at low voltage
s in the direct tunneling regime under the condition of electron injec
tion from the poly-Si gate. Soft breakdown of these ultra-thin oxide l
ayers, accompanied by the occurrence of complex fluctuations in the di
rect tunneling current, is demonstrated. Using this as the definition
of sub-3-nm oxide breakdown, it is shown for the first time that the t
ime to dielectric breakdown of the sub-3-nm gate oxide in the direct t
unneling regime is determined by the electrical field strength in the
oxide similarly to the case of the sub-3-nm dielectric breakdown in Fo
wler-Nordheim tunnel stressing.