Plymouth aerosol has been directly collected on to transmission electron mi
croscopy grids at both roadside and background sites at the University of P
lymouth. Photographs of 50 randomly selected particles were taken. The part
icle images were collected and measured using a Quantimet 570 image analyse
r. Two box-counting procedures approximating to fractal dimensions were app
lied to the collected particle images. Comparison of the fractal dimensions
of roadside and background particles shows there is a structural change in
particles from road to background in the 220-320 nm size range. Within thi
s range, roadside particles;are both more dense and have a more convoluted
surface than the same size aerosol in the background. It is reasonable to a
ssume that roadside particles will therefore have a deeper lung penetration
and greater surface loading of material than their counterparts in the bac
kground aerosol.