The electrostatic powder coating process is reviewed. Three basic regions o
f a powder coating system are considered. The charged powder source region
embraces corona and triboelectric guns. These are reviewed and particle cha
rging processes considered. The second region where charged powder transpor
t to the workpiece occurs is one in which aerodynamic, space charge, and gr
avitational forces act to determine particle trajectories. With corona sour
ces ions generally outnumber charged particles by 10 to 1 so that the space
charge due to charged particles is negligible compared to that of ions. Ch
arged particle deposition onto the workpiece, the third region, is affected
by the electric held of particles already deposited. Back ionisation may o
ccur if ions are present and lead to poor coating finish. The adhesion of c
harged particles to a workpiece is often greater than expected by considera
tion of image forces alone. (C) 1998 Elsevier Science B.V. All rights reser
ved.