Thermodynamic limit for dipolar media

Citation
S. Banerjee et al., Thermodynamic limit for dipolar media, J STAT PHYS, 93(1-2), 1998, pp. 109-141
Citations number
41
Categorie Soggetti
Physics
Journal title
JOURNAL OF STATISTICAL PHYSICS
ISSN journal
00224715 → ACNP
Volume
93
Issue
1-2
Year of publication
1998
Pages
109 - 141
Database
ISI
SICI code
0022-4715(199810)93:1-2<109:TLFDM>2.0.ZU;2-7
Abstract
We prove existence of a shape- and boundary-condition-independent thermodyn amic limit for fluids and solids of identical particles with electric or ma gnetic dipole moments. Our result applies to fluids of hard-core particles, to dipolar soft spheres and Stockmayer fluids, to disordered solid composi tes, and to regular crystal lattices. In addition to their permanent dipole moments, particles may further polarize each other. Classical and quantum models are treated. Shape independence depends on the reduction in free ene rgy accomplished by domain formation, so our proof applies only in the case of zero applied field. Existence of a thermodynamic limit implies texture formation in spontaneously magnetized liquids and disordered solids analogo us to domain formation in crystalline solids.