In recent years, compared to optical lithography that has optical limitatio
n, electron beam lithography has been applied in delineating selected layer
s of Gbit DRAM and VHSIC such as HEMT due to its high resolution. Chemicall
y amplified resists (CAR) have been broadly utilized for their high sensiti
vity and high resolution. This paper is a study on simulation models and ch
aracteristics for electron beam lithography with highly sensitive CAR. We p
ropose especially on a general analytic model for the chemical behavior of
positive tone resists with typical deprotection chemistries and negative to
ne resists with three components resist system. The model covers acid gener
ation, diffusion, reaction, soluble possibility in the developer and the de
velopment. The edge profiles and performances of resists are analyzed by us
ing a simulator and experiments, and the simulation shows a good agreement
with the actual process.