A polyhedral magnesium silicate with a Mg5Si4O10 framework: X-ray crystal structure of [{(2,6-i-Pr2C6H3)N(SiMe3SiMe3)SiO3}(2)-{(2,6-i-Pr2C6H3)N(SiMe3)SiO2(OH)}(2)(Mg center dot C4H8O)(5)]

Authors
Klemp, A Roesky, HW Schmidt, HG Park, HS Noltemeyer, M
Citation
A. Klemp et al., A polyhedral magnesium silicate with a Mg5Si4O10 framework: X-ray crystal structure of [{(2,6-i-Pr2C6H3)N(SiMe3SiMe3)SiO3}(2)-{(2,6-i-Pr2C6H3)N(SiMe3)SiO2(OH)}(2)(Mg center dot C4H8O)(5)], ORGANOMETAL, 17(24), 1998, pp. 5225-5227
Citations number
20
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
17
Issue
24
Year of publication
1998
Pages
5225 - 5227
Database
ISI
SICI code
0276-7333(19981123)17:24<5225:APMSWA>2.0.ZU;2-M
Abstract
The reaction, of (2,6-i-Pr(2)C(6)H3)N(SiMe3)Si(OH)(3) (1) with Bu2Mg in THF at room-temperature resulted in the formation of the magnesium silicate 2. The core of the molecule consists of two four-membered, two six-membered, and three eight-membered rings and can be regarded as a molecular magnesium silicate soluble in conventional organic solvents.