Regioselective addition of PRPh2 to the C-alpha atom of the diphenylallenylidene ligand of [Ru(eta(5)-C5H5) (C=C=CPh2)(CO)(PPR3i)]BF4

Authors
Esteruelas, MA Gomez, AV Lopez, AM Modrego, J Onate, E
Citation
Ma. Esteruelas et al., Regioselective addition of PRPh2 to the C-alpha atom of the diphenylallenylidene ligand of [Ru(eta(5)-C5H5) (C=C=CPh2)(CO)(PPR3i)]BF4, ORGANOMETAL, 17(24), 1998, pp. 5434-5436
Citations number
28
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
17
Issue
24
Year of publication
1998
Pages
5434 - 5436
Database
ISI
SICI code
0276-7333(19981123)17:24<5434:RAOPTT>2.0.ZU;2-#
Abstract
The allenylidene ligand of [Ru(eta(5)-C5H5){C = C=CPh2}(CO)(PPr3i)]BF4 adds PHPh2, PMePh2, and PPh3 selectively at the C-alpha atom, whereas OH- and [ OMe](-) are added at the C-gamma atom.