We report an observation of a change in the energy spectrum of a matter wav
e due to fast modulation in time. The experiment, carried out with slow neu
trons, achieved pulse widths of 33 n, and has been analyzed using time-depe
ndent optics based on the nonrelativistic Schrodinger equation. A good fit
to the data is obtained. The modulation of a matter wave in time leads to a
characteristic energy spread. These phenomena can be seen as a consequence
of the time-energy uncertainty relation. In our case, the amplitude modula
tion is done by a rapid periodic opening and closing of a slit. In the time
domain this causes a so-called ''diffraction in time." In this work we dem
onstrate the operation of a time-of-flight spectrometer (FOTOF), and achiev
e an energy resolution of 20 neV, which to our knowledge represents a new l
imit for a TOF with slow neutrons. [S1050-2947(98)04312-1].