Mineralogical fingerprints of industrial emissions - an example from Ni mining and smelting on the Kola Peninsula, NW Russia

Fifteen large (> 20 kg) snowpack samples, representing the atmospheric depo sition of one winter (1995/1996), were collected in the vicinity (1.5-8 km) of the copper-nickel processing plants on the Kola Peninsula, NW Russia. M icroscopical (reflected light) and electron microprobe investigations were carried out on polished sections of filter residues (> 0.45 mu m) of these samples to identify the mineralogical composition of the particulate deposi tion. The technique allows us to directly distinguish between particles ori ginating from geogenic sources (e.g. windblown rock dust) and additional an thropogenic input from industrial sources. Furthermore, it was possible to gain information on the metallurgical processes used in the different facto ries (one roasting plant and two smelters using different technology). Each industry emits a very characteristic spectrum of particulates. The mineral ogy of the particulate inpute can thus be directly used to unravel the sour ce of observed heavy metal inputs at any one place even in complex situatio ns with several industries located at close distance. (C) 1998 Elsevier Sci ence B.V. All rights reserved.