CuInSe2 (CIS) thin films were electrodeposited and characterized for photov
oltaic applications. As-deposited and selenized films exhibited different k
inds of morphology. The conductivity type, carrier concentration and flat-b
and potential were determined from photoelectrochemical studies. Schottky b
arrier type photovoltaic junctions were formed by using a heavily doped PMe
T (poly-3-methylthiophene, displaying nearly metallic behaviour) prepared b
y electropolymerization, and CIS obtained by electrodeposition. The photovo
ltaic structure formed and studied was an Mo/CIS/PMeT/grid Schottky barrier
junction. A corrected solar to electrical conversion efficiency of 1.4% wa
s obtained in the case of the PMeT/CIS junction.