Alkylation of dianions derived from 2-(1-iminoalkyl) phenols: Synthesis offunctionalized 2-acyl phenols.

Authors
Cimarelli, C Palmieri, G
Citation
C. Cimarelli et G. Palmieri, Alkylation of dianions derived from 2-(1-iminoalkyl) phenols: Synthesis offunctionalized 2-acyl phenols., TETRAHEDRON, 54(51), 1998, pp. 15711-15720
Citations number
16
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
54
Issue
51
Year of publication
1998
Pages
15711 - 15720
Database
ISI
SICI code
0040-4020(199812)54:51<15711:AODDF2>2.0.ZU;2-2
Abstract
A method has been developed for the almost exclusive C-alkylation of the 2- (1-iminoalkyl) phenols 1, important organic compounds with a range of emplo yment, which allows the preparation of complex derivatives 4 with good yiel ds starting from easily available materials. The operational simplicity of this method take advantages in providing a variety of alkylated 2-acyl phen ols 5 by an easy hydrolysis of the 2-(1-iminoalkyl) phenols 4. (C) 1998 Els evier Science Ltd. All rights reserved.