Synthesis and crystal structure of bis(triphenylphosphine)-decahydro-hypho-hexaborane[(PPh3)(2)B6H10]center dot CH2Cl2

Authors
Schaper, T Preetz, W
Citation
T. Schaper et W. Preetz, Synthesis and crystal structure of bis(triphenylphosphine)-decahydro-hypho-hexaborane[(PPh3)(2)B6H10]center dot CH2Cl2, Z NATURFO B, 53(11), 1998, pp. 1326-1328
Citations number
10
Categorie Soggetti
Chemistry
Journal title
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
ISSN journal
09320776 → ACNP
Volume
53
Issue
11
Year of publication
1998
Pages
1326 - 1328
Database
ISI
SICI code
0932-0776(199811)53:11<1326:SACSOB>2.0.ZU;2-A
Abstract
By reaction of [B6H6](2-) with (PPh3)(3)AgCl in dichloromethane the belt-sh aped hypho-hexaborane adduct [(PPh3)(2)B6H10] is formed. The crystal struct ure of [(PPh3)(2)B6H10].CH2Cl2 has been determined by single crystal x-ray diffraction analysis: orthorhombic, space group Pbnb with a = 9.804(3), b = 17.864(4), c = 21.334(2) Angstrom, Z = 4.