A linear-chain copper(I) coordination polymer with hexakis(methylthio)benzene

Authors
Suenaga, Y Kuroda-Sowa, T Munakata, M Maekawa, M Morimoto, H
Citation
Y. Suenaga et al., A linear-chain copper(I) coordination polymer with hexakis(methylthio)benzene, ACT CRYST C, 54, 1998, pp. 1566-1569
Citations number
16
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
54
Year of publication
1998
Part
11
Pages
1566 - 1569
Database
ISI
SICI code
0108-2701(19981115)54:<1566:ALCCPW>2.0.ZU;2-I
Abstract
In the structure of catena-poly [copper(I)-mu-[hexakis(methylthio)benzene-S -1,S-2:S-4,S-5]] hexafluorophosphate, {[Cu(C12H18S6)]PF6}(n), each Cu atom is coordinated to four S atoms of two hexakis(methylthio)benzene ligands in a tetrahedral arrangement to give a cationic linear-chain polymer. The ele ctrical resistivity of compacted pellets was measured by the conventional t wo-probe technique. Iodine-doped black products in powder form behave as a semiconductor with a conductivity of 1.5 x 10(-6) S cm(-1).