Aqua(4,4 '-dicarbomethoxy-2,2 '-bipyridine-N,N ')(3,6-dichloro-4,5-dihydroxy-1,2-benzoquinonato-O-4,O-5)copper(II) acetonitrile hemisolvate

Authors
Zheng, LM Schmalle, HW Ferlay, S Decurtins, S
Citation
Lm. Zheng et al., Aqua(4,4 '-dicarbomethoxy-2,2 '-bipyridine-N,N ')(3,6-dichloro-4,5-dihydroxy-1,2-benzoquinonato-O-4,O-5)copper(II) acetonitrile hemisolvate, ACT CRYST C, 54, 1998, pp. 1578-1580
Citations number
16
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
54
Year of publication
1998
Part
11
Pages
1578 - 1580
Database
ISI
SICI code
0108-2701(19981115)54:<1578:A'''>2.0.ZU;2-N
Abstract
The title compound, [CU(C6Cl2O4)(C14H12N2O4)(H2O)].0.5CH(3)CN, adopts a sli ghtly distorted square-pyramidal geometry around the five-coordinated Cu-II atoms, when the bidentate benzoquinone anion and the bidentate bipyridine ligand form the basal plane. The elongated apical position is occupied by a water molecule. The acetonitrile solvate molecule is disordered.