Dichloro(tetrahydrofuran-O)[tris(1-pyrazolyl-N-2)borato]vanadium(III)

Authors
Rehder, D Gailus, H Schmidt, H
Citation
D. Rehder et al., Dichloro(tetrahydrofuran-O)[tris(1-pyrazolyl-N-2)borato]vanadium(III), ACT CRYST C, 54, 1998, pp. 1590-1592
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
54
Year of publication
1998
Part
11
Pages
1590 - 1592
Database
ISI
SICI code
0108-2701(19981115)54:<1590:D>2.0.ZU;2-#
Abstract
The title compound, [HB(pz)(3)]VCl2(thf) or [VCl2(C9H10BN6)(C4H8O)] (pz = p yrazolyl, thf = tetrahydrofuran), is an analogue of the unknown eta(5)-CpVC l2 (Cp = cyclopentadienyl). The pyrazolyl complex was prepared from VCl3(th f)(3) and K[HB(pz)(3)]. The molecule adopts a structure comparable to the p iano-stool arrangement of a half-sandwich complex.