Di-mu-chloro-bis[chloro(eta(5)-indenyl)methyl-hafnium(IV)]

Authors
Morris, RJ Shaw, SL Huffman, JC Bollinger, JC
Citation
Rj. Morris et al., Di-mu-chloro-bis[chloro(eta(5)-indenyl)methyl-hafnium(IV)], ACT CRYST C, 54, 1998, pp. 1617-1618
Citations number
8
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
54
Year of publication
1998
Part
11
Pages
1617 - 1618
Database
ISI
SICI code
0108-2701(19981115)54:<1617:D>2.0.ZU;2-K
Abstract
The molecular structure of the title complex, [HfCl(mu- Cl)(CH3)(eta(5)-C9H 7)](2), which is a rare example of an indenylhafnium alkyl complex, is desc ribed. In this centrosymmetric structure, the geometry around each Hf atom is best described as a pseudo-square pyramid. There is a small amount of di sorder between the methyl groups and the terminal chloride ligands.