A bicyclic cyclopropane carboxylic acid lactone from a solid-liquid PTC reaction

Authors
Bocskei, Z Hell, Z Finta, Z Toke, L Simon, K
Citation
Z. Bocskei et al., A bicyclic cyclopropane carboxylic acid lactone from a solid-liquid PTC reaction, ACT CRYST C, 54, 1998, pp. 1694-1695
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
54
Year of publication
1998
Part
11
Pages
1694 - 1695
Database
ISI
SICI code
0108-2701(19981115)54:<1694:ABCCAL>2.0.ZU;2-E
Abstract
The structure of 6,6-dimethyl-4-trichloromethyl-3-oxabicyclo[3.1.0]hexan-2- one-1-carboxylic acid ethyl ester (C11H13Cl3O4), a potential pyrethroid-typ e intermediate, is presented. It is dominated by the interplanar angle [70. 1(3)degrees] formed by the lactone and the cyclopropane rings of the molecu le. A structural comparison with other related published structures is also presented.