2,4-Cl-2-6,9-exo,endo-(PMe2Ph)(2)-arachno-B10H10

Authors
Dorfler, U McGrath, TD Cooke, PA Kennedy, JD Thornton-Pett, M
Citation
U. Dorfler et al., 2,4-Cl-2-6,9-exo,endo-(PMe2Ph)(2)-arachno-B10H10, ACT CRYST C, 54, 1998, pp. 1703-1705
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
54
Year of publication
1998
Part
11
Pages
1703 - 1705
Database
ISI
SICI code
0108-2701(19981115)54:<1703:2>2.0.ZU;2-Q
Abstract
The title compound, 2,4-dichloro-6-exo-9-endo-bis(dimethylphenylphosphino)- arachno-decarborane(10) [(PMe2Ph)(2)B10H10Cl2 or C16H32B10C12P2], has a typ ical arachno ten-vertex cluster geometry, with one of the phosphine ligands bound exo-polyhedrally and the other in an uncommon endo configuration.