Synthesis and structure of a tetranuclear niobium telluride cuboidal cluster with a central mu(4)-O ligand

Authors
Fedin, VP Kalinina, IV Virovets, AV Podberezskaya, NV Neretin, IS Slovokhotov, YL
Citation
Vp. Fedin et al., Synthesis and structure of a tetranuclear niobium telluride cuboidal cluster with a central mu(4)-O ligand, CHEM COMMUN, (23), 1998, pp. 2579-2580
Citations number
31
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
23
Year of publication
1998
Pages
2579 - 2580
Database
ISI
SICI code
1359-7345(199812):23<2579:SASOAT>2.0.ZU;2-C
Abstract
High-temperature reaction of NbTe4 with KCN at 450 degrees C and further cr ystallization from aqueous solution produces an oxygen-centered tetranuclea r niobium cubane-type complex, isolated here as K-6[Nb4OTe4(CN)(12)]. K2CO3 . KOH . 8H(2)O, and characterized by X-ray crystallography.