[(silox)(2)ReO](2) (silox = (Bu3SiO)-Bu-t) contains a Re equivalent to Re bond and terminal oxo ligands

Authors
Douthwaite, RE Wolczanski, PT Merschrod, E
Citation
Re. Douthwaite et al., [(silox)(2)ReO](2) (silox = (Bu3SiO)-Bu-t) contains a Re equivalent to Re bond and terminal oxo ligands, CHEM COMMUN, (23), 1998, pp. 2591-2592
Citations number
26
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
23
Year of publication
1998
Pages
2591 - 2592
Database
ISI
SICI code
1359-7345(199812):23<2591:[(=(CA>2.0.ZU;2-B
Abstract
The preference for terminal rather than bridging {i.e. [(silox)(2)Re](2)(mu -O)(2)} oxo ligands in C-2 (silox)(2)(O)Re=Re(O)(silox)(2) is electronic, n ot steric, in origin.