I. Tworowska et W. Dabkowski, New efficient synthesis of phosphonofluorodithioates ROP(S)(S-)F and theirstructural analogues, CHEM COMMUN, (23), 1998, pp. 2611-2612
The title compounds 3 are formed in very high yield from a one-pot sequenti
al reaction of 1,3,2-dithiaphospholane pm derivatives 1, which are transfor
med into the corresponding PIV compounds 2 by addition of elemental sulfur
and finally into fluoridodithioates 3 by TBAF.